Equilibrium analysis and LSER modelling for extraction of Trans-aconitic acid using Tri-butyl Phosphate by using Xylene and Benzene

Authors

  • R. P. Nimbalkar  Assistant Professor, Department of Chemical Engineering, Priyadarshini Institute of Engineering & Technology, Nagpur Maharashtra,India
  • R. P. Ugwekar  Associate Professor, Department of Chemical Engineering, Laxminarayan Institute of Technology, Nagpur Maharashtra,India
  • S. R. Mote  Associate Professor, Department of Chemical Engineering, Priyadarshini Institute of Engineering & Technology, Nagpur Maharashtra, India

Keywords:

Trans-aconitic acid, Tri-butylphosphate, LSER, benzene, xylene

Abstract

Reactive extraction of Trans-aconitic acid from its aqueous solution has been carried out by Tri- butylphosphate as extractant and benzene, xylene as diluents. The study has been performed at room temperature and distribution coefficient (KD), extraction efficiency (E %) and equilibrium complexation constant (K11) has been found out. The maximum value of KD = 9.098454, E%=90.09749 was found out for 0.689219 mol/L trans-aconitic acid, 1.40733mol/L (40%) Tri- butylphosphate and benzene. The paper has presented linear solvation energy Relationship (LSER) model for trans-aconitic acid using tri-butyl phosphate in benzene, xylene.The LSER model with regression coefficient of 0.9845 is obtained. The model value is close to the experimental data.

References

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IInternational Journal of Scientific Research in Computer Science, Engineering and Information Technology

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Published

2019-12-30

Issue

Volume 4, Issue 9, November-December-2019

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Research Articles

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How to Cite

[1]
R. P. Nimbalkar, R. P. Ugwekar, S. R. Mote, " Equilibrium analysis and LSER modelling for extraction of Trans-aconitic acid using Tri-butyl Phosphate by using Xylene and Benzene" International Journal of Scientific Research in Computer Science, Engineering and Information Technology(IJSRCSEIT), ISSN : 2456-3307, Volume 4, Issue 9, pp.173-178, November-December-2019.